Substance   CYANOGEN BROMIDE
UN Number   1889
HIN (= Hazard Identification Number)   668
ADR Label   6.1+8
ADR Class   6.1
Classification Code   TC2
Packing group   I
ERIC   6-38
 
Emergency Response Information
HIGHLY TOXIC CORROSIVE SUBSTANCE

1. Characteristics
  • Gives off dangerous fumes.
  • Corrosive, causing damage to skin, eyes and air passages.
  • Highly toxic by ingestion, inhalation and skin absorption.
  • Flash point above 60°C OR not flammable.

2. Hazards
  • Heating of container(s) will cause pressure rise with risk of bursting and subsequent explosion.
  • Gives off toxic and corrosive fumes, also when burning.
  • May attack metals and produce hydrogen gas which may form explosive mixture with air.
  • The vapour may be invisible and is heavier than air. It spreads along the ground and may enter sewers and basements.

3. Personal Protection
  • Gas tight suit.

4. Intervention Actions
  4.1 General
  • PUBLIC SAFETY HAZARD - Warn people nearby to stay indoors with doors and windows closed. Stop any ventilation. Consider evacuation of people in immediate danger.
  • Keep upwind. Put on protective equipment before entering danger area.
  • Minimise number of personnel in risk area.

  4.2 Spillage
  • Stop leaks if possible.
  • Contain spillage by any means available.
  • Absorb liquid in sand or earth or any other suitable material.
  • If substance has entered a water course or sewer, inform the responsible authority.
  • Ventilate sewers and basements where there is no risk to personnel or public.
  • Knock down vapour cloud with water spray.
  • Consider covering liquid pool with alcohol resistant foam if necessary to reduce toxic vapour hazard.

  4.3 Fire (involving the substance)
  • Keep container(s) cool with water.
  • Extinguish with water fog (spray).
  • Do not use water jet to extinguish.
  • Use water spray to knock down fire fumes if possible.
  • Avoid unnecessary run-off of extinguishing media which may cause pollution.

5. First Aid
  • If substance has got into eyes, wash out with water for at least 15 minutes and seek immediate medical attention.
  • Remove contaminated clothing immediately and drench affected skin with plenty of water.
  • Persons who have been in contact with the substance or have inhaled fumes should get immediate medical attention. Pass on all available product information.
  • Mouth to mouth resuscitation should be avoided. Use alternative methods, preferably with oxygen or compressed air driven apparatus.

6. Essential Precautions For Product Recovery
  • Use acid resistant equipment.
  • Recover spilled product in hermetically sealed container.

7. Precautions After Intervention
  7.1 Undressing
  • Drench contaminated suit and breathing apparatus with water before removing facemask and suit.
  • Use chemical protection suit and self contained breathing apparatus while undressing contaminated co-workers or handling contaminated equipment.
  • Contain decontamination run off.

  7.2 Equipment Clean Up
  • Seek specialist advice before leaving incident.
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