ISOCYANATES, TOXIC, N.O.S. or ISOCYANATE SOLUTION, TOXIC, N.O.S.
UN Number
2206
HIN (= Hazard Identification Number)
60
ADR Label
6.1
ADR Class
6.1
Classification Code
T1
Packing group
II,III
ERIC
6-03
Emergency Response Information
TOXIC SUBSTANCE
1. Characteristics
Hazardous to skin, eyes and air passages.
Toxic by ingestion, inhalation or skin absorption.
Flash point above 60°C OR not flammable.
2. Hazards
Heating of container(s) will cause pressure rise with risk of bursting and subsequent explosion.
Gives off toxic and irritant fumes, also when burning.
The vapour may be invisible and is heavier than air. It spreads along the ground and may enter sewers and basements.
3. Personal Protection
Chemical protection suit.
Self contained breathing apparatus.
Gas tight suit in close proximity to substance or vapour.
4. Intervention Actions 4.1 General
Keep upwind. Put on protective equipment before entering danger area.
4.2 Spillage
Stop leaks if possible.
Contain spillage by any means available.
Absorb liquid in sand or earth or any other suitable material.
If substance has entered a water course or sewer, inform the responsible authority.
Ventilate sewers and basements where there is no risk to personnel or public.
4.3 Fire (involving the substance)
Keep container(s) cool with water.
Extinguish with water fog (spray).
Do not use water jet to extinguish.
Use water spray to knock down fire fumes if possible.
Avoid unnecessary run-off of extinguishing media which may cause pollution.
5. First Aid
If substance has got into eyes, wash out with water for at least 15 minutes and seek immediate medical attention.
Remove contaminated clothing immediately and drench affected skin with plenty of water.
Persons who have been in contact with the substance or have inhaled fumes should get immediate medical attention. Pass on all available product information.
Mouth to mouth resuscitation should be avoided. Use alternative methods, preferably with oxygen or compressed air driven apparatus.
6. Essential Precautions For Product Recovery
Recover spilled product in vented container fitted with absorption filter.
7. Precautions After Intervention 7.1 Undressing
Drench contaminated suit and breathing apparatus with water before removing facemask and suit.
Use chemical protection suit and self contained breathing apparatus while undressing contaminated co-workers or handling contaminated equipment.